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- W4242953223 abstract "An unprecedented nickel-catalyzed domino reductive cyclization of alkynes and o-bromoaryl aldehydes is described. The reaction features broad substrate scope and is tolerant of a variety of functional groups, providing straightforward access to biologically significant indanones and spiroindanone pyrrolidine derivatives in good yields with excellent regio- and diastereoselectivity. Preliminary mechanistic studies have shown that indanones are formed by the cyclization of o-bromoaryl aldehydes and alkynes to form indenol intermediates, followed by hydrogen autotransfer." @default.
- W4242953223 created "2022-05-12" @default.
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- W4242953223 date "2021-01-18" @default.
- W4242953223 modified "2023-10-01" @default.
- W4242953223 title "Synthesis of Indanones and Spiroindanones by Diastereoselective Annulation Based on a Hydrogen Autotransfer Strategy" @default.
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- W4242953223 doi "https://doi.org/10.1002/ange.202013792" @default.
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