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- W4242959619 abstract "The synthesis and characterization of an alternating pyridine-pyridazine strand comprising thirteen heterocycles are described. Spontaneous folding into a helical secondary structure is based on a general molecular self-organization process enforced by the conformational information encoded within the primary structure of the molecular strand itself. Conformational control based on heterocyclic helicity codons illustrates a strategy for designing folding properties into synthetic oligomers (foldamers). Strong intermolecular interactions of the highly ordered lock-washer subunits of compound 3 results in hierarchical supramolecular self-assembly into protofibrils and fibrils. Compound 3 also forms mechanically stable two-dimensional Langmuir-Blodgett and cast thin films." @default.
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- W4242959619 date "2002-08-02" @default.
- W4242959619 modified "2023-10-13" @default.
- W4242959619 title "Helical Self-Organization and Hierarchical Self-Assembly of an Oligoheterocyclic Pyridine–Pyridazine Strand into Extended Supramolecular Fibers" @default.
- W4242959619 doi "https://doi.org/10.1002/1521-3765(20020802)8:15<3448::aid-chem3448>3.0.co;2-" @default.
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