Matches in SemOpenAlex for { <https://semopenalex.org/work/W4242970423> ?p ?o ?g. }
Showing items 1 to 58 of
58
with 100 items per page.
- W4242970423 endingPage "204" @default.
- W4242970423 startingPage "199" @default.
- W4242970423 abstract "The molecular structures of trimethylchlorostannane in various donor solvents were investigated by far-IR spectroscopy. The absorption frequency associated with the SnCl stretching vibration was found to be linearly related to the solvent donor number. The ClSnC angles of the complex species in solution were evaluated from the ratio of the absorption intensities of the symmetrical and the asymmetric SnC stretching vibrations and were also found to be related to the solvent donor number. They form a continuous set of molecular geometries between tetrahedral and trigonal bipyramidal arrangements, the bipyramidal form being approached more closely as the solvent donor number is increased. The results obtained in this way were in agreement with those obtained by x-ray and electron diffraction and can be compared with those from 119 Sn and 1 H NMR spectroscopy. Alcohols appear to interact not only as donors through the oxygen atoms, but also as acceptors with the formation of OH ··· Cl bonds. The charge distribution and CSnCl angle (α CSnCl ), calculated for comparison by means of the semi-empirical MNDO method, react sensitively to changes in the distance between the tin atom and the donor." @default.
- W4242970423 created "2022-05-12" @default.
- W4242970423 creator A5057071944 @default.
- W4242970423 date "1990-01-01" @default.
- W4242970423 modified "2023-10-17" @default.
- W4242970423 title "Investigation of the solvation of trimethylchlorostannane using far-infrared spectroscopy" @default.
- W4242970423 doi "https://doi.org/10.1016/s0003-2670(00)86534-4" @default.
- W4242970423 hasPublicationYear "1990" @default.
- W4242970423 type Work @default.
- W4242970423 citedByCount "0" @default.
- W4242970423 crossrefType "journal-article" @default.
- W4242970423 hasAuthorship W4242970423A5057071944 @default.
- W4242970423 hasConcept C107872376 @default.
- W4242970423 hasConcept C113196181 @default.
- W4242970423 hasConcept C120665830 @default.
- W4242970423 hasConcept C121332964 @default.
- W4242970423 hasConcept C148093993 @default.
- W4242970423 hasConcept C153642686 @default.
- W4242970423 hasConcept C158355884 @default.
- W4242970423 hasConcept C178790620 @default.
- W4242970423 hasConcept C185592680 @default.
- W4242970423 hasConcept C32891209 @default.
- W4242970423 hasConcept C32909587 @default.
- W4242970423 hasConcept C62520636 @default.
- W4242970423 hasConcept C69607484 @default.
- W4242970423 hasConceptScore W4242970423C107872376 @default.
- W4242970423 hasConceptScore W4242970423C113196181 @default.
- W4242970423 hasConceptScore W4242970423C120665830 @default.
- W4242970423 hasConceptScore W4242970423C121332964 @default.
- W4242970423 hasConceptScore W4242970423C148093993 @default.
- W4242970423 hasConceptScore W4242970423C153642686 @default.
- W4242970423 hasConceptScore W4242970423C158355884 @default.
- W4242970423 hasConceptScore W4242970423C178790620 @default.
- W4242970423 hasConceptScore W4242970423C185592680 @default.
- W4242970423 hasConceptScore W4242970423C32891209 @default.
- W4242970423 hasConceptScore W4242970423C32909587 @default.
- W4242970423 hasConceptScore W4242970423C62520636 @default.
- W4242970423 hasConceptScore W4242970423C69607484 @default.
- W4242970423 hasIssue "2" @default.
- W4242970423 hasLocation W42429704231 @default.
- W4242970423 hasOpenAccess W4242970423 @default.
- W4242970423 hasPrimaryLocation W42429704231 @default.
- W4242970423 hasRelatedWork W16393301 @default.
- W4242970423 hasRelatedWork W17055897 @default.
- W4242970423 hasRelatedWork W2251600 @default.
- W4242970423 hasRelatedWork W23871980 @default.
- W4242970423 hasRelatedWork W24940698 @default.
- W4242970423 hasRelatedWork W26675287 @default.
- W4242970423 hasRelatedWork W27602699 @default.
- W4242970423 hasRelatedWork W5311475 @default.
- W4242970423 hasRelatedWork W6408339 @default.
- W4242970423 hasRelatedWork W16489452 @default.
- W4242970423 hasVolume "240" @default.
- W4242970423 isParatext "false" @default.
- W4242970423 isRetracted "false" @default.
- W4242970423 workType "article" @default.