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- W4242983013 abstract "The first asymmetric total synthesis of the antifeedant terpenoids (+)-norleucosceptroid A, (−)-norleucosceptroid B, and (−)-leucosceptroid K has been accomplished. This highly concise synthetic route was guided by our efforts to develop a platform for the collective synthesis of a whole family of antifeedant natural products. The synthesis features a Hauser–Kraus-type annulation followed by an unprecedented, highly efficient intramolecular dilactol aldol-type condensation reaction to produce the 5,6,5 skeleton. The developed synthetic route proceeds for norleucosceptroid A and B in 16 steps (longest linear sequence) from known compounds." @default.
- W4242983013 created "2022-05-12" @default.
- W4242983013 creator A5021374480 @default.
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- W4242983013 date "2014-09-04" @default.
- W4242983013 modified "2023-09-26" @default.
- W4242983013 title "A General Entry to Antifeedant Sesterterpenoids: Total Synthesis of (+)-Norleucosceptroid A, (−)-Norleucosceptroid B, and (−)-Leucosceptroid K" @default.
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- W4242983013 doi "https://doi.org/10.1002/ange.201407788" @default.
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