Matches in SemOpenAlex for { <https://semopenalex.org/work/W4243155403> ?p ?o ?g. }
Showing items 1 to 87 of
87
with 100 items per page.
- W4243155403 endingPage "261" @default.
- W4243155403 startingPage "257" @default.
- W4243155403 abstract "ABSTRACT Urocanic acid, imidazole propenoic acid, is a metabolic product of histidine, which accumulates in skin and is excreted in sweat. It absorbs UV radiation at wavelengths shorter than 340 nm, and its principal photochemical reaction is a trans‐cis isomerization about the propenyl double bond. This isomerization to the biologically active cis isomer is implicated in the photo‐induced suppression of the immune system of skin. The kinetics of the trans → cis photoisomerization of urocanic acid has been determined in a number of solvents, spanning a range of polarities. The initial rates of isomerization and the photostationary trans‐cis compositions, in all solvents except water, correlate linearly with solvent polarity. This indicates that the isomerization proceeds through a polar intermediate that is stabilized by coulombic interactions with the molecular environment." @default.
- W4243155403 created "2022-05-12" @default.
- W4243155403 creator A5006471110 @default.
- W4243155403 creator A5020751680 @default.
- W4243155403 creator A5057357174 @default.
- W4243155403 date "2004-09-01" @default.
- W4243155403 modified "2023-10-17" @default.
- W4243155403 title "The Effect of Molecular Environment on the Photoisomerization of Urocanic Acid¶" @default.
- W4243155403 cites W1967793984 @default.
- W4243155403 cites W1977632425 @default.
- W4243155403 cites W1982105556 @default.
- W4243155403 cites W1990086231 @default.
- W4243155403 cites W1996085867 @default.
- W4243155403 cites W1996854850 @default.
- W4243155403 cites W2005104469 @default.
- W4243155403 cites W2017497107 @default.
- W4243155403 cites W2025671884 @default.
- W4243155403 cites W2027710928 @default.
- W4243155403 cites W2033629406 @default.
- W4243155403 cites W2035461587 @default.
- W4243155403 cites W2039116243 @default.
- W4243155403 cites W2063484524 @default.
- W4243155403 cites W2085280423 @default.
- W4243155403 cites W2094800180 @default.
- W4243155403 cites W2124852032 @default.
- W4243155403 cites W2139520918 @default.
- W4243155403 cites W2142527896 @default.
- W4243155403 cites W2147265765 @default.
- W4243155403 cites W2159542307 @default.
- W4243155403 cites W2161938636 @default.
- W4243155403 cites W2227796832 @default.
- W4243155403 cites W2336723294 @default.
- W4243155403 cites W4238910744 @default.
- W4243155403 cites W4299505732 @default.
- W4243155403 cites W2093729723 @default.
- W4243155403 doi "https://doi.org/10.1111/j.1751-1097.2004.tb00080.x" @default.
- W4243155403 hasPublicationYear "2004" @default.
- W4243155403 type Work @default.
- W4243155403 citedByCount "2" @default.
- W4243155403 crossrefType "journal-article" @default.
- W4243155403 hasAuthorship W4243155403A5006471110 @default.
- W4243155403 hasAuthorship W4243155403A5020751680 @default.
- W4243155403 hasAuthorship W4243155403A5057357174 @default.
- W4243155403 hasConcept C126661725 @default.
- W4243155403 hasConcept C161790260 @default.
- W4243155403 hasConcept C178790620 @default.
- W4243155403 hasConcept C185592680 @default.
- W4243155403 hasConcept C2776381347 @default.
- W4243155403 hasConcept C2778460671 @default.
- W4243155403 hasConcept C515207424 @default.
- W4243155403 hasConcept C55493867 @default.
- W4243155403 hasConcept C68381374 @default.
- W4243155403 hasConcept C75473681 @default.
- W4243155403 hasConcept C85311670 @default.
- W4243155403 hasConcept C86048148 @default.
- W4243155403 hasConceptScore W4243155403C126661725 @default.
- W4243155403 hasConceptScore W4243155403C161790260 @default.
- W4243155403 hasConceptScore W4243155403C178790620 @default.
- W4243155403 hasConceptScore W4243155403C185592680 @default.
- W4243155403 hasConceptScore W4243155403C2776381347 @default.
- W4243155403 hasConceptScore W4243155403C2778460671 @default.
- W4243155403 hasConceptScore W4243155403C515207424 @default.
- W4243155403 hasConceptScore W4243155403C55493867 @default.
- W4243155403 hasConceptScore W4243155403C68381374 @default.
- W4243155403 hasConceptScore W4243155403C75473681 @default.
- W4243155403 hasConceptScore W4243155403C85311670 @default.
- W4243155403 hasConceptScore W4243155403C86048148 @default.
- W4243155403 hasIssue "2" @default.
- W4243155403 hasLocation W42431554031 @default.
- W4243155403 hasOpenAccess W4243155403 @default.
- W4243155403 hasPrimaryLocation W42431554031 @default.
- W4243155403 hasRelatedWork W1981121502 @default.
- W4243155403 hasRelatedWork W1999794847 @default.
- W4243155403 hasRelatedWork W2003848024 @default.
- W4243155403 hasRelatedWork W2058600553 @default.
- W4243155403 hasRelatedWork W2070614168 @default.
- W4243155403 hasRelatedWork W2132941556 @default.
- W4243155403 hasRelatedWork W4233233375 @default.
- W4243155403 hasRelatedWork W4243155403 @default.
- W4243155403 hasRelatedWork W4253909294 @default.
- W4243155403 hasRelatedWork W51427894 @default.
- W4243155403 hasVolume "80" @default.
- W4243155403 isParatext "false" @default.
- W4243155403 isRetracted "false" @default.
- W4243155403 workType "article" @default.