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- W4243201238 abstract "Abstract We developed the novel one‐pot synthetic method of substituted triptycenes by the reaction of ynolates and arynes. This four‐step process involves three cycloadditions and electrocyclic ring opening of the strained Dewar anthracene. Each of the three related but structurally distinct classes of nucleophiles (ynolate, enolate, and anthracenolate) reacts with o‐benzyne in the same predictable manner controlled by chelation and negative hyperconjugation. The resulting functionalized C 3 ‐symmetrical triptycenes hold promise in the design of functional materials." @default.
- W4243201238 created "2022-05-12" @default.
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- W4243201238 date "2016-12-28" @default.
- W4243201238 modified "2023-10-10" @default.
- W4243201238 title "Regioselective One‐Pot Synthesis of Triptycenes via Triple‐Cycloadditions of Arynes to Ynolates" @default.
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- W4243201238 doi "https://doi.org/10.1002/ange.201609111" @default.
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