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- W4243320275 abstract "Abstract The LaF 3 , structure has previously been described in the space group P6 3 /mmc with two formula units per unit cell. Weak additional reflections on single-crystal photographs lead to a larger unit cell with a = 7.190 ± 0.002 Å, c = 7.367 ± 0.002 Å, space group P3̄c1, and six LaF 3 per unit cell. The structure has been refined by full-matrix least-squares computations. The deviation from the high symmetry is caused by displacements of the F ions. LaF 3 is shown to be isotypic with HoD 3 . The- calculated ionic-lattice energy (-1151.6 kcal/ mole) agrees with the energy calculated by a Born-Haber cycle (- 1144.4 kcal/ mole). The probable critical radius ratio for the change from the LaF 3 to the orthorhombic YF 3 structure is 0.94. For smaller ratios the LaF 3 structure can be stabilized by anion vacancies." @default.
- W4243320275 created "2022-05-12" @default.
- W4243320275 creator A5035619574 @default.
- W4243320275 date "1965-12-01" @default.
- W4243320275 modified "2023-09-30" @default.
- W4243320275 title "Die Kristall struktur von Lanthantrifluorid" @default.
- W4243320275 doi "https://doi.org/10.1515/zkri-1965-1-638" @default.
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