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- W4243323571 abstract "<div>We study the structural and thermomechanical effects</div><div>of cation substitution in the compositional family of</div><div>metal–organic frameworks Zn1xCdx(mIm)2 (HmIm = 2-</div><div>methylimidazole). We find complete miscibility for all</div><div>compositions x, with evidence of inhomogeneous distributions of Cd and Zn that in turn affect framework aperture characteristics. Using variable-temperature X-ray powder diffraction measurements, we show that Cd substitution drives a threefold reduction in the magnitude of thermal expansion behaviour. We interpret this effect in terms of an increased density of negative thermal expansion modes in the more flexible Cd-rich frameworks.</div>" @default.
- W4243323571 created "2022-05-12" @default.
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- W4243323571 date "2018-01-01" @default.
- W4243323571 modified "2023-10-17" @default.
- W4243323571 title "Compositional Inhomogeneity and Tuneable Thermal Expansion in Mixed-Metal ZIF-8 Analogues" @default.
- W4243323571 doi "https://doi.org/10.26434/chemrxiv.6355802" @default.
- W4243323571 hasPublicationYear "2018" @default.
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