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- W4243383046 abstract "THE eleventh volume of Dr. Mellor's “Comprehensive Treatise” includes the element tellurium, held over from the previous volume on sulphur and selenium, and the half-brothers of the oxygen family, chromium, molybdenum, and tungsten, but without uranium. All these elements raise interesting problems of valency; but the section on the valency of tellurium is unfortunately already out of date, since the evidence cited on p. 32 for the coplanar configuration of the four radicals in the telluronium salts has been obsolete since the end of 1928, whilst positive evidence of the tetra-hedral configuration was provided at the end of 1929. The chromium ammines are catalogued with characteristic thoroughness under ninety subheadings, and stereo-isomerism is suggested as a possible explanation of the existence of multiple forms of certain members of the series, but the index contains no references by which general phenomena, such as co-ordination, isomerism, or stereo-isomerism, can be discovered. On the other hand, the interesting oxy-salts, which are so characteristic of this family of elements, can be traced quite readily by referring to entries under chromyl, molybdenyl, and uranyl compounds." @default.
- W4243383046 created "2022-05-12" @default.
- W4243383046 date "1931-12-01" @default.
- W4243383046 modified "2023-09-27" @default.
- W4243383046 title "Chemistry" @default.
- W4243383046 doi "https://doi.org/10.1038/128957a0" @default.
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