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• W4243403120 abstract "Abstract CF 3 ‐substituted 1,3‐diols were stereoselectively prepared in excellent enantiopurity and high yield from CF 3 ‐substituted diketones by using an ansa‐ruthenium(II)‐catalyzed asymmetric transfer hydrogenation in formic acid/triethylamine. The intermediate mono‐reduced alcohol was also obtained in very high enantiopurity by applying milder reaction conditions. In particular, CF 3 C(O)‐substituted benzofused cyclic ketones underwent either a single or a double dynamic kinetic resolution during their reduction." @default.
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• W4243403120 date "2016-03-22" @default.
• W4243403120 modified "2023-09-26" @default.
• W4243403120 title "Stereoarrayed CF3 -Substituted 1,3-Diols by Dynamic Kinetic Resolution: Ruthenium(II)-Catalyzed Asymmetric Transfer Hydrogenation" @default.
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• W4243403120 doi "https://doi.org/10.1002/ange.201600812" @default.
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