Matches in SemOpenAlex for { <https://semopenalex.org/work/W4243412084> ?p ?o ?g. }
- W4243412084 endingPage "9923" @default.
- W4243412084 startingPage "9919" @default.
- W4243412084 abstract "Introduced herein is a series of conjugated thienylboranes, which are inert to air and moisture, and even resist acids and strong bases. X-ray analyses reveal a coplanar arrangement of the thiophene rings, an arrangement which facilitates p–π conjugation through the boron atoms despite the presence of highly bulky 2,4,6-tri-tert-butylphenyl (Mes*) or 2,4,6-tris(trifluoromethyl)phenyl (FMes) groups. Short B⋅⋅⋅F contacts, which lead to a pseudotrigonal bipyramidal geometry in the FMes species, have been further studied by DFT and AIM analysis. In contrast to the Mes* groups, the highly electron-withdrawing FMes groups do not diminish the Lewis acidity of boron toward F− anions. These compounds can be lithiated or iodinated under electrophilic conditions without decomposition, thus offering a promising route to larger conjugated structures with electron-acceptor character." @default.
- W4243412084 created "2022-05-12" @default.
- W4243412084 creator A5009600298 @default.
- W4243412084 creator A5028225823 @default.
- W4243412084 creator A5040146694 @default.
- W4243412084 creator A5063667229 @default.
- W4243412084 creator A5067894921 @default.
- W4243412084 date "2014-07-17" @default.
- W4243412084 modified "2023-10-18" @default.
- W4243412084 title "Highly Electron-Deficient and Air-Stable Conjugated Thienylboranes" @default.
- W4243412084 cites W1553330920 @default.
- W4243412084 cites W1560526107 @default.
- W4243412084 cites W1901176552 @default.
- W4243412084 cites W1964760434 @default.
- W4243412084 cites W1966035598 @default.
- W4243412084 cites W1969434044 @default.
- W4243412084 cites W1970209677 @default.
- W4243412084 cites W1971944586 @default.
- W4243412084 cites W1973368088 @default.
- W4243412084 cites W1984001131 @default.
- W4243412084 cites W1998983839 @default.
- W4243412084 cites W2014451515 @default.
- W4243412084 cites W2015124874 @default.
- W4243412084 cites W2019070167 @default.
- W4243412084 cites W2019512570 @default.
- W4243412084 cites W2026010834 @default.
- W4243412084 cites W2027230661 @default.
- W4243412084 cites W2031142571 @default.
- W4243412084 cites W2032475221 @default.
- W4243412084 cites W2033065759 @default.
- W4243412084 cites W2036297858 @default.
- W4243412084 cites W2054729462 @default.
- W4243412084 cites W2056551967 @default.
- W4243412084 cites W2063131088 @default.
- W4243412084 cites W2063536471 @default.
- W4243412084 cites W2063851575 @default.
- W4243412084 cites W2065742318 @default.
- W4243412084 cites W2077104814 @default.
- W4243412084 cites W2077134292 @default.
- W4243412084 cites W2088121833 @default.
- W4243412084 cites W2091258582 @default.
- W4243412084 cites W2093951445 @default.
- W4243412084 cites W2095193265 @default.
- W4243412084 cites W2118033614 @default.
- W4243412084 cites W2121715335 @default.
- W4243412084 cites W2122746064 @default.
- W4243412084 cites W2124065737 @default.
- W4243412084 cites W2126383912 @default.
- W4243412084 cites W2133300466 @default.
- W4243412084 cites W2138711861 @default.
- W4243412084 cites W2141007283 @default.
- W4243412084 cites W2159688465 @default.
- W4243412084 cites W2315932724 @default.
- W4243412084 cites W2318313377 @default.
- W4243412084 cites W2321476763 @default.
- W4243412084 cites W2326105069 @default.
- W4243412084 cites W2331751649 @default.
- W4243412084 cites W2332053416 @default.
- W4243412084 cites W2333449069 @default.
- W4243412084 cites W2502076792 @default.
- W4243412084 cites W4235288695 @default.
- W4243412084 cites W4245919778 @default.
- W4243412084 cites W4250308490 @default.
- W4243412084 cites W4254883721 @default.
- W4243412084 doi "https://doi.org/10.1002/ange.201403700" @default.
- W4243412084 hasPublicationYear "2014" @default.
- W4243412084 type Work @default.
- W4243412084 citedByCount "53" @default.
- W4243412084 countsByYear W42434120842014 @default.
- W4243412084 countsByYear W42434120842015 @default.
- W4243412084 countsByYear W42434120842016 @default.
- W4243412084 countsByYear W42434120842017 @default.
- W4243412084 countsByYear W42434120842018 @default.
- W4243412084 countsByYear W42434120842019 @default.
- W4243412084 countsByYear W42434120842020 @default.
- W4243412084 countsByYear W42434120842021 @default.
- W4243412084 countsByYear W42434120842022 @default.
- W4243412084 countsByYear W42434120842023 @default.
- W4243412084 crossrefType "journal-article" @default.
- W4243412084 hasAuthorship W4243412084A5009600298 @default.
- W4243412084 hasAuthorship W4243412084A5028225823 @default.
- W4243412084 hasAuthorship W4243412084A5040146694 @default.
- W4243412084 hasAuthorship W4243412084A5063667229 @default.
- W4243412084 hasAuthorship W4243412084A5067894921 @default.
- W4243412084 hasConcept C112613896 @default.
- W4243412084 hasConcept C121332964 @default.
- W4243412084 hasConcept C124681953 @default.
- W4243412084 hasConcept C155647269 @default.
- W4243412084 hasConcept C161790260 @default.
- W4243412084 hasConcept C163638829 @default.
- W4243412084 hasConcept C178790620 @default.
- W4243412084 hasConcept C185592680 @default.
- W4243412084 hasConcept C26873012 @default.
- W4243412084 hasConcept C2776442012 @default.
- W4243412084 hasConcept C2779892579 @default.
- W4243412084 hasConcept C2779953032 @default.
- W4243412084 hasConcept C2780263894 @default.
- W4243412084 hasConcept C2900893 @default.