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- W4243417539 abstract "The phosphorescence spectrum of pyrimidine has been studied at 90°K in various media, such as ethanol, dioxane, cyclohexane and benzene. The phosphorescence has a lifetime of about 10−2sec. The spectrum in cyclohexane consists of well-resolved bands but in other solvents it shows diffuse structure. Vibrational analyses of the spectrum are discussed mainly for the spectrum in cyclohexane. Results of solvent effects on the phosphorescence spectrum suggest that the observed triplet-singlet transition of pyrimidine is 3B2(n, π∗) → 1A1, and that the second excited (π, π∗) triplet level is located just above the (n, π∗) triplet level." @default.
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- W4243417539 date "1961-01-01" @default.
- W4243417539 modified "2023-09-23" @default.
- W4243417539 title "The lowest multiplicity-forbidden transitions in diazines—II" @default.
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- W4243417539 doi "https://doi.org/10.1016/0371-1951(61)80008-8" @default.
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