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- W4243673875 abstract "The polarographic behavior of dithiole-thiones in DMF depends on the nature of substituent R4. When R4 is a methyl group a 2 e cathodic wave is observed. When R4 is H, two, apparently 1 e, cathodic waves are observed. The first can be ascribed to a reversible monoelectronic reduction yielding an organomercurial. The second in fact corresponds to the occurrence of the same 2 e cathodic process as observed when R4 is a methyl group. The 2 e process occurs at ca. −1050 mV vs. aqueous SCE and this potential does not markedly depend on the nature of R4 and/or R5. The 2 e reduction product is either the cyclic dianion (A2−) when R4 is H and R5 is phenyl group, or a mixture of (A2−) and A2− when R4 and/or R5 is a methyl group. The redox couple (A2−)/A exhibits reversible behavior at the mercury electrode." @default.
- W4243673875 created "2022-05-12" @default.
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- W4243673875 date "1983-05-10" @default.
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- W4243673875 title "Electrochemical behavior of 1,2-dithiole-3-thiones" @default.
- W4243673875 doi "https://doi.org/10.1016/0368-1874(83)80147-6" @default.
- W4243673875 hasPublicationYear "1983" @default.
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