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- W4243706192 abstract "Abstract A series of highly emissive inert and chiral Cr III complexes displaying dual circularly polarized luminescence (CPL) within the NIR region have been prepared and characterized. The helical [Cr(dqpR) 2 ] 3+ (dqp=2,6‐di(quinolin‐8‐yl)pyridine; R=OCH 3 , Br or C≡CH) complexes were synthesized as racemic mixtures and resolved into their respective PP and MM enantiomers by chiral stationary phase HPLC. The corresponding enantiomers show large g lum ≈0.2 and high quantum yield of up to 17 %, which afford important CPL brightness of up to 170 m −1 cm −1 , a key point for applications as chiral luminescent probes. Moreover, the long‐lived CP‐NIR emission provided by these chromophores (ms range) in aqueous solution opens the way toward the quantification of chiral targets in biological systems with time‐gated detection. Thus, such chiral chromophores based on earth abundant and inert 3d metals open new perspectives in the field of CPL and represent an alternative to precious 4d, 5d and to labile 4f metal‐based complexes." @default.
- W4243706192 created "2022-05-12" @default.
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- W4243706192 date "2021-03-11" @default.
- W4243706192 modified "2023-10-14" @default.
- W4243706192 title "Bright Long‐Lived Circularly Polarized Luminescence in Chiral Chromium(III) Complexes" @default.
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- W4243706192 cites W1971053045 @default.
- W4243706192 cites W1974256758 @default.
- W4243706192 cites W1996178269 @default.
- W4243706192 cites W2002395165 @default.
- W4243706192 cites W2005351547 @default.
- W4243706192 cites W2016049407 @default.
- W4243706192 cites W2020927295 @default.
- W4243706192 cites W2031469590 @default.
- W4243706192 cites W2033979606 @default.
- W4243706192 cites W2041049135 @default.
- W4243706192 cites W2048422869 @default.
- W4243706192 cites W2054316210 @default.
- W4243706192 cites W2063334919 @default.
- W4243706192 cites W2081370066 @default.
- W4243706192 cites W2094219230 @default.
- W4243706192 cites W2106662470 @default.
- W4243706192 cites W2119771384 @default.
- W4243706192 cites W2130602510 @default.
- W4243706192 cites W2136168875 @default.
- W4243706192 cites W2148642364 @default.
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- W4243706192 cites W2419503320 @default.
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- W4243706192 cites W2496618181 @default.
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- W4243706192 cites W2592502069 @default.
- W4243706192 cites W2604183684 @default.
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- W4243706192 cites W2624094034 @default.
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- W4243706192 cites W2790436722 @default.
- W4243706192 cites W2792248583 @default.
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- W4243706192 cites W3004337398 @default.
- W4243706192 cites W3010861410 @default.
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- W4243706192 cites W3045866647 @default.
- W4243706192 cites W3046167311 @default.
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- W4243706192 doi "https://doi.org/10.1002/ange.202101158" @default.
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