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- W4243750916 abstract "Changes in vibrational absorption and vibrational circular dichroism (VCD) spectra of polyribocytidylic acid (polyC) in buffered D2O solution as a function of pH and temperature are reported. Analysis of these spectral data led us to establish the absorption band at ∼1693 cm-1 and associated negative VCD couplet as diagnostic markers of the double-helical form of polyC. An alternate interpretation suggesting quadruplex formation for polyC is also discussed. In addition to the solution state spectral data, pH-dependent absorption and VCD spectra for polyC films derived from dilute H2O solutions are also presented. The pH-dependent changes in the absorption and VCD spectra of polyC films are found to be similar to those observed for polyC in solution." @default.
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- W4243750916 date "2006-10-24" @default.
- W4243750916 modified "2023-10-16" @default.
- W4243750916 title "Structural Transitions in Polyribocytidylic Acid Induced by Changes in pH and Temperature: Vibrational Circular Dichroism Study in Solution and Film States" @default.
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- W4243750916 doi "https://doi.org/10.1021/jp063221l" @default.
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