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- W4244271009 abstract "Abstract A seven‐step enantioselective total synthesis of (−)‐terengganensine A, a complex heptacyclic monoterpene indole alkaloid, was accomplished. Key steps included: a) Noyori's catalytic enantioselective transfer hydrogenation of the iminium salt to set up the absolute configuration at the C21 position; b) a highly diastereoselective C7 benzoyloxylation with dibenzoyl peroxide under mild conditions; and c) an integrated one‐pot oxidative cleavage of cyclopentene/triple cyclization/hydrolysis sequence for the construction of the dioxa azaadamantane motif with complete control of four newly generated stereocenters." @default.
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- W4244271009 date "2016-04-20" @default.
- W4244271009 modified "2023-10-02" @default.
- W4244271009 title "Enantioselective Total Synthesis of (−)-Terengganensine A" @default.
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- W4244271009 doi "https://doi.org/10.1002/ange.201602374" @default.
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