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- W4244297390 abstract "Frustrated delivery: Frustrated Lewis pairs derived from tBu3P and Al(C6F5)3 activate H2 to give [tBu3PH][(μ-H)(Al(C6F5)3)2], which reacts with unactivated olefins to give RAl(C6F5)2 (R=Et or Cy) and [tBu3PH][Al(C6F5)4]. The proposed mechanism involves olefin activation by aluminum, which is supported by the isolation of the cyclohexene complex [Al(C6F5)3⋅(C6H10)]. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
- W4244297390 created "2022-05-12" @default.
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- W4244297390 date "2012-07-09" @default.
- W4244297390 modified "2023-10-18" @default.
- W4244297390 title "H2 Activation and Hydride Transfer to Olefins by Al(C6F5)3-Based Frustrated Lewis Pairs" @default.
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- W4244297390 doi "https://doi.org/10.1002/anie.201203362" @default.
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