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• W4244385743 abstract "Infrared spectra of N4-hydroxycytosine isolated in argon and nitrogen low-temperature matrixes are reported. The compound was found to adopt the syn structure of the imino-oxo tautomeric form exclusively. A photoreaction (lambda > 250 nm) converting this form into the anti isomer was observed. The reaction is reversible and leads to a photostationary point. The initial infrared spectrum and the spectrum of the photoproduct were assigned to the syn and anti isomers, respectively. This assignment is based on a close agreement between the experimental spectra and the spectra theoretically simulated at the DFT(B3LYP)/6-31++G** level of theory." @default.
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• W4244385743 date "2001-01-01" @default.
• W4244385743 modified "2023-10-18" @default.
• W4244385743 title "Photochemical syn–anti Isomerization Reaction in N4-Hydroxycytosine. An Experimental Matrix Isolation and Theoretical Study" @default.
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• W4244385743 doi "https://doi.org/10.1562/0031-8655(2001)074<0253:psairi>2.0.co;2" @default.
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