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- W4244497029 abstract "The kinetics of ruthenium(III) chloride catalysis in the oxidation of diethylene glycol (DG) and methyl diethylene glycol (MDG) by N-bromo-acetamide (NBA) in perchloric acid media are reported. The reactions follow identical kinetics, showing zero-order dependence on NBA, but first-order on each of H+, Ru(III) and Cl− ions. The first-order kinetics with respect to glycol at low concentrations shifts to zero-order at higher concentrations. A negative effect of ionic strength is observed, while successive addition of acetamide, D2O and mercuric acetate shows zero effect on the reaction rate. Various activation parameters have been computed. The products of the reactions were identified as the corresponding acids. A suitable mechanism consistent with the kinetic observations has been proposed." @default.
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- W4244497029 date "1988-11-01" @default.
- W4244497029 modified "2023-09-26" @default.
- W4244497029 title "Mechanism of Ru(III) catalysis in N-bromoacetamide oxidation of some glycols in perchloric acid media" @default.
- W4244497029 doi "https://doi.org/10.1016/0304-5102(88)85006-5" @default.
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