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- W4244501079 abstract "Crystallization in the metastable zone of a solute–solvent system or molten phase can occur when some amount of supersaturation or supercooling is created in the system experimentally either by a polythermal or an isothermal method. This chapter deals with the processes of crystallization of solids from solutions and melts at predefined temperatures. It describes the processes associated with the crystallization of polymorphs. The chapter also describes various approaches advanced to explain the kinetics of crystallization. It discusses that the solubility of different compounds, including polymorphs of a particular compound, increases with a decrease in their melting points and that the interfacial energy of different compounds decreases with their increasing solubility. The chapter provides some experimental data of evolution of phase transformation of metastable phases to stable ones in different solvents. The Kolmogorov–Johnson–Mehl–Avrami (KJMA) theory provides information on the dimensionality of growing crystallites as well as on the nucleation and growth processes." @default.
- W4244501079 created "2022-05-12" @default.
- W4244501079 date "2018-07-24" @default.
- W4244501079 modified "2023-10-12" @default.
- W4244501079 title "Phase Transformation and Isothermal Crystallization Kinetics" @default.
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- W4244501079 doi "https://doi.org/10.1002/9781119461616.ch4" @default.
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