Matches in SemOpenAlex for { <https://semopenalex.org/work/W4244555558> ?p ?o ?g. }
Showing items 1 to 70 of
70
with 100 items per page.
- W4244555558 endingPage "26" @default.
- W4244555558 startingPage "19" @default.
- W4244555558 abstract "Three trifluorobenzenes were prepared by reaction of the corresponding trichlorobenzenes with potassium fluoride or pottassium fluoride-cesium fluoride mixtures in dimethyl sulfone. Molar yields were 12.8% for 1,2,3-, 8.3% for 1,2,4-, and 56.2% for 1,3,5-. Improved yields of the 1,2,3- (23.9%) and the 1,2,4- (34.0%) trifluorobenzenes were obtained from certain partially fluorinated intermediates. Several chlorofluorobenzene intermediates were obtained in goods yields by careful control of the reaction variables. The instability of the polyfluorobenzenes in the halogen-exchange reaction medium explains, in part, why only limited yields of the polyfluorobenzenes are obtained by using this method." @default.
- W4244555558 created "2022-05-12" @default.
- W4244555558 creator A5063512563 @default.
- W4244555558 creator A5067604069 @default.
- W4244555558 creator A5072611718 @default.
- W4244555558 date "1972-07-01" @default.
- W4244555558 modified "2023-10-14" @default.
- W4244555558 title "Fluorination of 1,2,3-, 1,2,4-, and 1,3,5-trihalobenzenes with potassium fluoride in dimethyl sulfone" @default.
- W4244555558 cites W1991576044 @default.
- W4244555558 cites W1993075463 @default.
- W4244555558 cites W2020006929 @default.
- W4244555558 cites W2029138475 @default.
- W4244555558 cites W2047762956 @default.
- W4244555558 cites W2063920692 @default.
- W4244555558 cites W2087128221 @default.
- W4244555558 cites W2090947711 @default.
- W4244555558 doi "https://doi.org/10.1016/s0022-1139(00)83111-5" @default.
- W4244555558 hasPublicationYear "1972" @default.
- W4244555558 type Work @default.
- W4244555558 citedByCount "10" @default.
- W4244555558 countsByYear W42445555582012 @default.
- W4244555558 countsByYear W42445555582016 @default.
- W4244555558 crossrefType "journal-article" @default.
- W4244555558 hasAuthorship W4244555558A5063512563 @default.
- W4244555558 hasAuthorship W4244555558A5067604069 @default.
- W4244555558 hasAuthorship W4244555558A5072611718 @default.
- W4244555558 hasConcept C155647269 @default.
- W4244555558 hasConcept C161790260 @default.
- W4244555558 hasConcept C178790620 @default.
- W4244555558 hasConcept C179104552 @default.
- W4244555558 hasConcept C185592680 @default.
- W4244555558 hasConcept C2778806918 @default.
- W4244555558 hasConcept C2779881495 @default.
- W4244555558 hasConcept C2780263894 @default.
- W4244555558 hasConcept C2780828025 @default.
- W4244555558 hasConcept C2994067411 @default.
- W4244555558 hasConcept C46062151 @default.
- W4244555558 hasConcept C517785266 @default.
- W4244555558 hasConceptScore W4244555558C155647269 @default.
- W4244555558 hasConceptScore W4244555558C161790260 @default.
- W4244555558 hasConceptScore W4244555558C178790620 @default.
- W4244555558 hasConceptScore W4244555558C179104552 @default.
- W4244555558 hasConceptScore W4244555558C185592680 @default.
- W4244555558 hasConceptScore W4244555558C2778806918 @default.
- W4244555558 hasConceptScore W4244555558C2779881495 @default.
- W4244555558 hasConceptScore W4244555558C2780263894 @default.
- W4244555558 hasConceptScore W4244555558C2780828025 @default.
- W4244555558 hasConceptScore W4244555558C2994067411 @default.
- W4244555558 hasConceptScore W4244555558C46062151 @default.
- W4244555558 hasConceptScore W4244555558C517785266 @default.
- W4244555558 hasIssue "1" @default.
- W4244555558 hasLocation W42445555581 @default.
- W4244555558 hasOpenAccess W4244555558 @default.
- W4244555558 hasPrimaryLocation W42445555581 @default.
- W4244555558 hasRelatedWork W1966012006 @default.
- W4244555558 hasRelatedWork W1977734081 @default.
- W4244555558 hasRelatedWork W2043546478 @default.
- W4244555558 hasRelatedWork W2153556453 @default.
- W4244555558 hasRelatedWork W2606553273 @default.
- W4244555558 hasRelatedWork W2606708251 @default.
- W4244555558 hasRelatedWork W2740094085 @default.
- W4244555558 hasRelatedWork W2950357450 @default.
- W4244555558 hasRelatedWork W3158069817 @default.
- W4244555558 hasRelatedWork W4292263890 @default.
- W4244555558 hasVolume "2" @default.
- W4244555558 isParatext "false" @default.
- W4244555558 isRetracted "false" @default.
- W4244555558 workType "article" @default.