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- W4244842171 abstract "The electron impact mass spectrometric fragmentation patterns of the per-O-trimethylsilyl (TMS) and alkoxime-TMS derivatives of D-glycerol-D-altro and D-glycerol-D-ido-octuloses were fully analysed using seven specifically labelled 13C analogues. Many of the more intense- ions in the spectra of the per-O-TMS furanose and pyranose derivatives have more than one origin. On the other hand, the mass spectra of the straight-chain methoxime and ethoxime hepta-O-TMS derivatives contain ions each of which in general originares from a single cleavage process. This makes gas chromatography/mass spectrometry of the aikoxime-TMS derivatives a suitable method for monitoring 13C incorporations at individual carbon atoms in the corresponding octulose phosphates during photosynthesis experiments with 13CO2." @default.
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- W4244842171 date "1992-10-01" @default.
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- W4244842171 title "Mass spectrometric studies of the path of carbon in photosynthesis: Positional isotopic analysis of13C-labelled 2-octulose phosphates" @default.
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- W4244842171 doi "https://doi.org/10.1002/oms.1210271015" @default.
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