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- W4244845535 abstract "This chapter presents a brilliant approach for modern isolation and structure elucidation of alkaloids. It includes background, in-depth information about isolation processes and structural characterization as well as a Q&A section. Pseudopelletierine is derived from the root-bark of the pomegranate tree. The chapter explains the the synthesis of cyclooctatetraene (COT) from pseudopelletierine. COT is not planar but in its most stable form exists in a tub-shaped conformation. Basic alkaloids occur in plants most often with a protonated amino function, i.e. in cationic form. The basicity of the alkaloid is used to differentiate it from the other lipophilic, organic substances. Pseudopelletierine is a homologue of tropinone. Pseudopelletierine proved to be a stroke of luck for the up-and-coming organic chemistry of the 20th century. The root-bark of the pomegranate tree is a speciality and a natural product that is not always commercially available." @default.
- W4244845535 created "2022-05-12" @default.
- W4244845535 date "2019-01-30" @default.
- W4244845535 modified "2023-09-25" @default.
- W4244845535 title "Alkaloids" @default.
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- W4244845535 doi "https://doi.org/10.1002/9783527806508.ch1" @default.
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