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- W4244854906 abstract "Die FeIV-S-Bindung von P450-Eisenoxen 1 weist eine kleine Dissoziationsenergie auf (6.3 kcal mol−1), und die Länge der Bindung ist, dank Charge Transfer vom Liganden-Schwefelatom auf den Porphyrinring, mit nur geringem Energieaufwand veränderbar. P450-Eisenoxen ist ein „Redoxmesomeriehybrid“, das durch die Fe-S-Bindungslänge und die Polarität der Umgebung beeinflusst wird." @default.
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- W4244854906 date "2000-11-03" @default.
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- W4244854906 title "The High-Valent Compound of Cytochrome P450: The Nature of the Fe−S Bond and the Role of the Thiolate Ligand as an Internal Electron Donor" @default.
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- W4244854906 doi "https://doi.org/10.1002/1521-3757(20001103)112:21<4009::aid-ange4009>3.0.co;2-v" @default.
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