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- W4245003721 abstract "Sperrige Substituenten führen zu einer hohen Barriere für die Isomerisierung der helical chiralen Enantiomere des Titel-Triarylborans (siehe Bild), was die Enantiomerentrennung durch chirale Chromatographie erlaubt. Die elektronischen Eigenschaften des zentralen Boratoms sind wesentlich für den Umklappvorgang der Propellerstruktur, und UV-Licht beschleunigt die Racemisierung erheblich. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
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- W4245003721 date "2011-06-21" @default.
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- W4245003721 title "Enantioseparation and Electronic Properties of a Propeller-Shaped Triarylborane" @default.
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- W4245003721 doi "https://doi.org/10.1002/ange.201101406" @default.
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