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- W4245023633 abstract "The synthesis of highly negatively charged polyoxometalates with electrically and structurally controlled uniform basic sites can lead to the unique base catalysis. In this work, a γ-Keggin germanodecatungstate, [γ-HGeW10O36]7− (A), having a −7 charge was, for the first time, successfully synthesized by the reaction of [γ-H2GeW10O36]6− with one equivalent of [(n-C4H9)4N]OH under non-aqueous conditions. The activities of germanodecatungstates for base-catalyzed reactions dramatically increased with increase in the number negative charges from −6 to −7. In the presence of A, various combinations of acylating agents and primary alcohols including those with acid-sensitive functional groups chemoselectively gave the desired acylated products in high yields even under the stoichiometric conditions." @default.
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- W4245023633 date "2014-09-26" @default.
- W4245023633 modified "2023-10-03" @default.
- W4245023633 title "A Basic Germanodecatungstate with a −7 Charge: Efficient Chemoselective Acylation of Primary Alcohols" @default.
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- W4245023633 doi "https://doi.org/10.1002/ange.201405212" @default.
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