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• W4245274498 abstract "The oxygen reduction characteristics of metalloporphyrins adsorbed at monolayer levels on a high surface area carbon, Norit BRX, have been studied in 8 N H2SO4 and also in 6N KOH. In an acid, oxygen reduction activity is found to be correlated with the MeII/MeIII redox potential. Most Co complexes have too high a redox potential, while too low a redox potential is observed for Fe, Ru, Os, Mn, and Cr. Ir porphyrins have the highest activity. In KOH, Ru porphyrins show the best performance. A heat treatment improves activity and stability strongly in an acid, but only mildly in an alkaline solution. A mechanism is proposed for oxygen reduction on transition metal chelates, both in acid and in alkaline solutions." @default.
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• W4245274498 date "1981-09-01" @default.
• W4245274498 modified "2023-10-18" @default.
• W4245274498 title "Oxygen Reduction on Transition-Metal Porphyrins in Acid Electrolyte I. Activity" @default.
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• W4245274498 doi "https://doi.org/10.1002/bbpc.19810850917" @default.
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