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• W4245393438 endingPage "9525" @default.
• W4245393438 startingPage "9517" @default.
• W4245393438 abstract "The molar conductivities Lambda of KBr and KI in dilute methanol solutions were measured along the liquid-vapor coexistence curve up to the critical temperature (240 degrees C). The concentration dependence of Lambda in each condition was analyzed by the Fuoss-Chen-Justice equation to obtain the limiting molar conductivities and the molar association constants. Using the present data together with the literature ones, the validity of the Hubbard-Onsager (HO) dielectric friction theory based on the sphere-in-continuum model was examined for the translational friction coefficients zeta of the halide ions (the Cl(-), Br(-), and I(-) ions) in methanol in the density range of 2.989rho(c)> or =rho> or =1.506rho(c), where rho(c)=0.2756 g cm(-3) is the critical density of methanol. For all the halide ions studied, the friction coefficient decreased with decreasing density at rho>2.0rho(c), while the nonviscous contribution Deltazeta/zeta increased; Deltazeta was defined as the difference between zeta and the friction coefficient estimated by the Stokes law. The density dependence of zeta and Deltazeta/zeta were well reproduced by the HO theory at rho>2.0rho(c). The HO theory also explained the ion-size dependence of Deltazeta/zeta which decreased with ion-size at rho>2.0rho(c). At rho<2.0rho(c), on the other hand, the HO theory could not explain the density and the ion-size dependences of zeta and Deltazeta/zeta. These results indicated that the application limit of the HO theory lied about rho=2.0rho(c) which is the same as the application limit observed for the alkali metal ions. The present results were also compared with the results in subcritical aqueous solutions." @default.
• W4245393438 created "2022-05-12" @default.
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• W4245393438 date "2004-11-04" @default.
• W4245393438 modified "2023-09-25" @default.
• W4245393438 title "Electric conductivities of 1:1 electrolytes in liquid methanol along the liquid-vapor coexistence curve up to the critical temperature. II. KBr and KI solutions" @default.
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• W4245393438 doi "https://doi.org/10.1063/1.1797211" @default.
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