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• W4245449462 abstract "Lignin is a thermoplastic polymer with high-impact strength and heat-resistance. After being compounded with a thermoplastic polymer matrix, it can improve the flowability and processing performance of the material. Moreover, the 3D network structured lignin molecules have shown significant enhancement in modifying materials by virtue of their relatively high rigidity. Currently, lignin-modified thermoplastic materials can be prepared by various processing methods after blending lignin or its derivatives with a variety of thermoplastic polymers. These thermoplastic polymers include polyethylene (PE), polypropylene (PP), polyvinyl chloride (PVC), polymethylmethacrylate (PMMA), polyvinyl alcohol (PVA), ethylene-vinyl acetate copolymer (EVA), polyester, starch, and protein. The methods of blending include melt-blending and solution mixing. The melt-blending system can be subjected to thermal processing methods such as extrusion, compression, injection, and blow-molding. Casting molding is generally applied in solutions mixing system. Studies about the structure and properties of lignin-modified thermoplastics have proved that, in lignin/polyester systems, the hydrogen bonds between the carbonyl groups on polyester matrix and the hydroxyl groups on lignin can improve their compatibility and the overall performance of the composite material. In the lignin/polylefin system, the various polar groups in lignin restrict the compatibility of lignin in the nonpolar matrix. Therefore, to improve the performance of such composite material, introducing compatibilizers or reaction compatiblization in melting blending are usually applied during the blending to increase interaction of its microphases. Lignin also can be added as filler into thermoplastic natural polymers such as starch or proteins to improve the mechanical properties, water resistance, and thermal stability of the composite material. This chapter focuses on the processing and molding methods of lignin-modified thermoplastics, including typical synthetic and natural polymer-based material systems. The structure-performances relationship of these materials and their application are discussed in detail." @default.
• W4245449462 created "2022-05-12" @default.
• W4245449462 date "2019-01-01" @default.
• W4245449462 modified "2023-09-27" @default.
• W4245449462 title "Lignin-Modified Thermoplastic Materials" @default.
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• W4245449462 doi "https://doi.org/10.1016/b978-0-12-813941-7.00005-9" @default.
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