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- W4245453032 endingPage "15132" @default.
- W4245453032 startingPage "15125" @default.
- W4245453032 abstract "Abstract A bowl‐shaped nitrogen‐doped nanographene composed of a pyrrolo[3,2‐b]pyrrole core substituted with six arene rings circularly bonded with one another has been prepared via a concise synthetic strategy encompassing the multicomponent tetraarylpyrrolopyrrole (TAPP) synthesis, the Scholl reaction, and intramolecular direct arylation. This synthesis represents the first case of programmed sequential intramolecular direct arylation reactions utilizing the different reactivity of C–Br and C–Cl bonds. The target compound contains two central pentagons confined between two adjacent heptagons—the inverse Stone–Thrower–Wales topology. The presence of both five‐ and seven‐membered rings in the final structure is responsible for interesting properties such as a perpendicularly aligned dipole moment, absorption and fluorescence in the orange‐red region, weak emission originating from the charge‐transfer character of a low‐energy absorption band, and a high lying HOMO. In the solid state slipped convex‐to‐convex π–π stacking dominates." @default.
- W4245453032 created "2022-05-12" @default.
- W4245453032 creator A5022419114 @default.
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- W4245453032 creator A5059150780 @default.
- W4245453032 creator A5063867141 @default.
- W4245453032 date "2021-05-07" @default.
- W4245453032 modified "2023-10-09" @default.
- W4245453032 title "Bowl‐Shaped Pentagon‐ and Heptagon‐Embedded Nanographene Containing a Central Pyrrolo[3,2‐ <i>b</i> ]pyrrole Core" @default.
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- W4245453032 doi "https://doi.org/10.1002/ange.202104092" @default.
- W4245453032 hasPublicationYear "2021" @default.
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