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• W4245504829 abstract "The identification and characterization of defects, on the molecular level, in metal-organic frameworks (MOFs) remain a challenge. With the extensive use of single-crystal X-ray diffraction (SXRD), the missing linker defects in the zirconium-based MOF UiO-66, Zr6O4(OH)4(C8H4O4)6, have been identified as water molecules coordinated directly to the zirconium centers. Charge balancing is achieved by hydroxide anions, which are hydrogen bonded within the pores of the framework. Furthermore, the precise nature of the defects and their concentration can be manipulated by altering the starting materials, synthesis conditions, and post-synthetic modifications." @default.
• W4245504829 created "2022-05-12" @default.
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• W4245504829 date "2015-08-07" @default.
• W4245504829 modified "2023-10-18" @default.
• W4245504829 title "Definitive Molecular Level Characterization of Defects in UiO-66 Crystals" @default.
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• W4245504829 doi "https://doi.org/10.1002/ange.201505461" @default.
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