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- W4245576296 abstract "The reactions of meso-1, 2, 3, 4-tetrachlorobutane (TCB) and 3, 4-dichloro-1-butene (3, 4-DCB1) with sodium hydroxide in aqueous alcohols were performed at 30°C in order to see the effects of the nature of alcohols upon the rates of the reactions. The consumption rate of TCB was found to decrease in the order: i-PrOH s-BuOH EtOH PrOH i-BuOH BuOH C51-1110H C8H130H Me0H. A similar reactivity order was observed in the case of 3, 4-DCB-1: i-PrOH PrOH Et0H s-BuOH i-BuOH BuOH C51-1110H C61-1180H Me0H. The trends may be explained in terms of the inductive and steric effects of alkyl groups on the nucleophilicity of alkoxide anions." @default.
- W4245576296 created "2022-05-12" @default.
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- W4245576296 date "1979-01-01" @default.
- W4245576296 modified "2023-09-27" @default.
- W4245576296 doi "https://doi.org/10.1246/nikkashi.1979.1612" @default.
- W4245576296 hasPublicationYear "1979" @default.
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