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• W4245586110 startingPage "4329" @default.
• W4245586110 abstract "Deprotonation of the yttrium–arsine complex [Cp′3Y{As(H)2Mes}] (1) (Cp′=η5-C5H4Me, Mes=mesityl) by nBuLi produces the μ-arsenide complex [{Cp′2Y[μ-As(H)Mes]}3] (2). Deprotonation of the AsH bonds in 2 by nBuLi produces [Li(thf)4]2[{Cp′2Y(μ3-AsMes)}3Li], [Li(thf)4]2[3], in which the dianion 3 contains the first example of an arsinidene ligand in rare-earth metal chemistry. The molecular structures of the arsine, arsenide, and arsinidene complexes are described, and the yttrium–arsenic bonding is analyzed by density functional theory." @default.
• W4245586110 created "2022-05-12" @default.
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• W4245586110 date "2015-02-05" @default.
• W4245586110 modified "2023-09-23" @default.
• W4245586110 title "Yttrium Complexes of Arsine, Arsenide, and Arsinidene Ligands" @default.
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• W4245586110 doi "https://doi.org/10.1002/ange.201500173" @default.
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