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- W4245589800 abstract "Rotational analyses of the first four bands in the ν1 progression of the C̃1B2←X̃1A1 transition of SeO2 at 312.7 nm are reported. The gas phase sample, which contained selenium isotopes in natural abundance, was formed in a free jet expansion from a heated nozzle source. The rotational constants for the C̃1B2 state show a rather erratic dependence on v1′, consistent with the identification of small, local perturbations in the rotational structure. The A-rotational constant shows a particularly irregular dependence on v1′. The r0 structure was therefore determined from the B and C values of 80SeO2 to be:r0=170.909(72)pmandθ0=103.954(7)°.The increase in r0 and decrease in θ0 on electronic excitation are consistent with the molecular orbital descriptions of the C̃1B2 and X̃1A1 states of SeO2. A strong hot band underlies the 103 band and somewhat devalues a earlier rotational analysis of this band by King and McLean [J. Mol. Spectrosc. 52 (1974) 154]. The isotopic shift of the band origins is also somewhat irregular. A comparison with the analogous C̃1B2←X̃1A1 transition of SO2 is presented." @default.
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- W4245589800 date "2004-06-01" @default.
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- W4245589800 title "The 313nm band system of SeO2. Part 2: rotational structure" @default.
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- W4245589800 doi "https://doi.org/10.1016/j.jms.2004.03.006" @default.
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