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- W4245630368 abstract "This chapter outlines the mechanisms, theoretical models and applications of primary crystal nucleation and secondary nucleation in batch or continuous crystallization process. Particular emphasis is placed on the control and optimization of organic polymorphs, crystal size and size distribution in the frameworks of primary spontaneous nucleation mechanisms (classical nucleation theory (CNT) and nonclassical mechanisms) and secondary nucleation mechanism. The experimental and computer simulation studies of ionic materials such as calcium carbonate, proteins, and some small organic molecular crystals suggest much more complex crystallization pathways, mainly including two-step mechanism and prenucleation clusters (PNCs). The two-step mechanism helps explain the nucleation kinetics of proteins. Its applicability relies on the existence of disordered transient clusters in solution prior to the formation of crystal nucleus. The application of PNCs pathway in explaining the crystallization of crystalline polymorphs appears to be promising." @default.
- W4245630368 created "2022-05-12" @default.
- W4245630368 creator A5031831764 @default.
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- W4245630368 date "2018-09-08" @default.
- W4245630368 modified "2023-09-27" @default.
- W4245630368 title "Nucleation" @default.
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- W4245630368 doi "https://doi.org/10.1002/9781119046233.ch2" @default.
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