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- W4245651323 abstract "[12716-12-6] C12H27P (MW 202.32) InChI = 1S/C12H27P/c1-10(2,3)13(11(4,5)6)12(7,8)9/h1-9H3 InChIKey = BWHDROKFUHTORW-UHFFFAOYSA-N (supporting ligand for palladium-1 and rhodium-catalyzed2 cross-coupling reactions) Physical Data: mp 30 °C; bp 102–103 °C/13 Torr; d 0.812 g cm−3. Solubility: sol in most organic solvents; insol in H2O. Form Supplied: colorless liquid or low-melting solid; approx. 10%(w/w) solution in hexane; or as HBF4 salt as a white solid; widely available in all forms. Purification: by vacuum distillation (102–103 °C, 13 Torr). Handling, Storage, and Precautions: the pure material is pyrophoric and must be handled under an oxygen-free atmosphere to avoid spontaneous combustion. In the absence of oxygen, it is indefinitely stable. Solutions (ca. 10%) of tri-tert-butylphosphine are not pyrophoric, but should be handled under an inert atmosphere in order to avoid oxidation to the phosphine oxide. The HBF4 salt is air-stable. Tri-tert-butylphosphine is corrosive and causes burns on contact with skin. It is incompatible with oxidizing agents." @default.
- W4245651323 created "2022-05-12" @default.
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- W4245651323 date "2007-03-15" @default.
- W4245651323 modified "2023-09-29" @default.
- W4245651323 title "Tri-tert-butylphosphine" @default.
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- W4245651323 doi "https://doi.org/10.1002/047084289x.rn00703" @default.
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