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- W4245674893 abstract "Abstract A new strategy for the three‐component addition of halide anions and acetylenes to donor–acceptor cyclopropanes (DACs) is presented. This reaction, which occurs with high E selectivity, is promoted by gallium(III) salts and based on the 1,2‐zwitterionic reactivity of DACs. It opens up a new group of processes involving DACs. The reaction occurs readily with a broad range of substrates and is tolerant of various functional groups. This methodology makes it possible to assemble highly functionalized vinyl halides, which are very convenient building blocks in organic synthesis. A possible mechanism of this reaction and its stereochemical aspects are discussed in detail." @default.
- W4245674893 created "2022-05-12" @default.
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- W4245674893 date "2018-07-18" @default.
- W4245674893 modified "2023-10-16" @default.
- W4245674893 title "Three‐Component Gallium(III)‐Promoted Addition of Halide Anions and Acetylenes to Donor–Acceptor Cyclopropanes" @default.
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- W4245674893 doi "https://doi.org/10.1002/ange.201803541" @default.
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