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- W4245685997 abstract "The pyrolysis of polynuclear aromatic compounds and their mixtures produces carbonaceous pitchlike residues and ultimately carbon and graphite. Reaction studies on model aromatic hydrocarbons can be used to illustrate the chemical changes involved in this complex process. The reactions largely involve aromatic polymerizations accompanied by bond cleavage and rearrangement. The tendency of large polynuclear aromatic compounds to associate into a liquid crystalline state plays a key role in their conversion to carbon. Studies using electron paramagnetic resonance—electron nuclear double resonance can clarify the nature of the stable free radicals that develop during carbonization. These aspects are reviewed to provide a clearer understanding of the chemistry involved in the transformation of polynuclear aromatic compounds to carbon." @default.
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- W4245685997 date "1987-12-22" @default.
- W4245685997 modified "2023-09-26" @default.
- W4245685997 title "Thermal Conversion of Polynuclear Aromatic Compounds to Carbon" @default.
- W4245685997 doi "https://doi.org/10.1021/ba-1988-0217.ch016" @default.
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