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- W4245690950 abstract "Regelverstoß: Das Umschalten von der üblichen 5-exo-Cyclisierung von Epoxidsubstraten auf den 6-endo-Modus, der Baldwins Regel widerspricht, charakterisiert die Reaktionen von Bishomoepoxyalkoholen mit Triisopropylsilyltriflat (TIPSOTf) in Nitromethan (siehe Schema). Diese Methode unterscheidet sich von früher beschriebenen, bei denen aufwändige Modifizierungen des Epoxidsubstrats erforderlich waren, um die 6-endo-Cyclisierung zu bewirken." @default.
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- W4245690950 date "2006-01-17" @default.
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- W4245690950 title "Reagent-Controlled Switching of 5-exo to 6-endo Cyclizations in Epoxide Openings" @default.
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- W4245690950 doi "https://doi.org/10.1002/ange.200503143" @default.
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