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- W4245723415 abstract "The norbornadiene/ethylene copolymerization was studied using [Ph2C(Ind)(Cp)ZrCl2] and [Cp2ZrCl2] catalysts in the presence of methylaluminoxane as a cocatalyst. The polymerizations were carried out using a semiflow method, and the comonomer was charged batchwise into the reactor. Polymerizations were run at 60°C at an ethylene pressure of 2.5 bar. The activities of both catalysts decreased when the norbornadiene/ethylene ratio in the reaction increased. The structural characterization of the copolymer was performed by DEPT and 1H-13C 2D NMR experiments. The copolymerization of norbornadiene was shown to occur via both double bonds of norbornadiene. The polymers with high norbornadiene content were amorphous and transparent." @default.
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- W4245723415 date "1999-12-01" @default.
- W4245723415 modified "2023-09-25" @default.
- W4245723415 title "Synthesis and characterization of poly(ethylene-co-norbornadiene)" @default.
- W4245723415 doi "https://doi.org/10.1002/(sici)1521-3935(19991201)200:12<2623::aid-macp2623>3.3.co;2-a" @default.
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