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- W4245942114 abstract "The application of the third-law method to the determination of the E parameters in cases of free-surface decomposition of MgSO 4 and BaSO 4 in vacuum and investigation of the effect of oxygen in reactor atmosphere on the rate of MgSO 4 decomposition allowed to support the dissociative evaporation mechanism of decomposition of these sulfates with releasing of atomic oxygen as one of the primary products. The experimental values of the E parameter for MgSO 4 and BaSO 4 are equal to 335.7±1.7 and 411±4 kJ mol −1 . The serious difference in decomposition temperatures in vacuum (about 1000 and 1400 K) and the E parameters for these two sulfates is connected with the difference in transfer of condensation energy of oxides to the reactants. In cases of MgSO 4 and BaSO 4 , the values of τ parameter are 0.42 and 0. Dependence of the τ parameter on the ratio of the equivalent pressure to the saturation pressure of corresponding metal oxide has been revealed from a comparison of τ parameters reported in the literature for eight different reactants. This correlation is of prime consideration for understanding of the mechanism of consumption of the condensation energy by the reactant." @default.
- W4245942114 created "2022-05-12" @default.
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- W4245942114 date "2003-09-11" @default.
- W4245942114 modified "2023-09-27" @default.
- W4245942114 title "Kinetics of free-surface decomposition of magnesium and barium sulfates analyzed thermogravimetrically by the third-law method" @default.
- W4245942114 doi "https://doi.org/10.1016/s0040-6031(03)00415-5" @default.
- W4245942114 hasPublicationYear "2003" @default.
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