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- W4246029927 abstract "The cw dye laser excitation spectrum of the Ã1A″(000) ← X̃1A′(000) vibronic band of HCF was observed between 17 188 and 17 391 cm−1 with the Doppler-limited resolution, 0.04 cm−1. The HCF molecule was produced by the reaction of discharged CF4 with CH3F, and 853 lines were observed, of which 516 transitions were assigned to K′a ← K″a = 3 ← 4, 2 ← 3, 1 ← 2, 0 ← 1, 1 ← 0, 2 ← 1, 0 ← 0, 1 ← 1, 2 ← 2, 3 ← 3, 2 ← 0, and 0 ← 2 subbands. A rotational analysis yielded the rotational constants and quartic and sextic centrifugal distortion constants for both the à and X̃ states and the band origin, with good precision. The molecular constants determined reproduce the observed transition frequencies with an average deviation of 0.0038 cm−1. Small rotational perturbations in the excited state were found at J = 5, 6 and J = 10, 11 of J1,J and at J = 15, 16 of J2,J−1 levels." @default.
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- W4246029927 date "1981-08-01" @default.
- W4246029927 modified "2023-10-16" @default.
- W4246029927 title "Doppler-limited dye laser excitation spectroscopy of HCF" @default.
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- W4246029927 doi "https://doi.org/10.1016/0022-2852(81)90181-8" @default.
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