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- W4246050446 abstract "Rapid and accurate detection of phenolic wastewater from industries has created global concern. Herein, core–shell magnetic cellulose nanocrystal supported MOF (Fe3O4/CNC@ZIF-8) with robust peroxidase-like activity was synthesized with tannic acid as modifier and bridge. The peroxidase-mimic catalytic activity of as-prepared Fe3O4/CNC@ZIF-8 was further investigated using o-phenylenediamine (OPD) as peroxidase substrates in the presence of H2O2. Moreover, the experimental conditions were optimized and the kinetic analysis results showed that Fe3O4/CNC@ZIF-8 had higher affinity towards both the substrate OPD and H2O2 than horseradish peroxidase (HRP). Finally, a phenol colorimetric assay with a linear range of 2–200 µM and a detection limit of 0.316 µM was constructed. The catalytic mechanism of Fe3O4/CNC@ZIF-8 with phenol was further investigated by fluorescence test and the generated ·OH was proved to act a crucial role to produce quinoid radicals. Additionally, the synthesized magnetic material had excellent stability and recyclability and ease to separation. These results suggest that the Fe3O4/CNC@ZIF-8 may be one of the promising candidates as peroxidase mimic for colorimetric detection of phenol." @default.
- W4246050446 created "2022-05-12" @default.
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- W4246050446 date "2021-08-07" @default.
- W4246050446 modified "2023-10-17" @default.
- W4246050446 title "Core–shell magnetic Fe3O4/CNC@MOF composites with peroxidase-like activity for colorimetric detection of phenol" @default.
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- W4246050446 doi "https://doi.org/10.1007/s10570-021-04117-w" @default.
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