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• W4246057841 startingPage "14445" @default.
• W4246057841 abstract "The reaction of [W(O)(CHCMe2Ph)(dAdPO)2], containing bulky 2,6-diadamantyl aryloxide ligands, with partially dehydroxylated silica selectively yields a well-defined silica-supported alkylidene complex, [(SiO)W(O)(CHCMe2Ph)(dAdPO)]. This fully characterized material is a very active and stable alkene metathesis catalyst, thus allowing loadings as low as 50 ppm in the metathesis of internal alkenes. [(SiO)W(O)(CHCMe2Ph)(dAdPO)] also efficiently catalyzes the homocoupling of terminal alkenes, with turnover numbers exceeding 75 000 when ethylene is constantly removed to avoid the formation of the less reactive square-based pyramidal metallacycle resting state." @default.
• W4246057841 created "2022-05-12" @default.
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• W4246057841 date "2014-10-15" @default.
• W4246057841 modified "2023-10-07" @default.
• W4246057841 title "Bulky Aryloxide Ligand Stabilizes a Heterogeneous Metathesis Catalyst" @default.
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• W4246057841 doi "https://doi.org/10.1002/ange.201408880" @default.
• W4246057841 hasPublicationYear "2014" @default.
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