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- W4246087343 abstract "Nanoparticles of cobalt phosphide, CoP, have been prepared and evaluated as electrocatalysts for the hydrogen evolution reaction (HER) under strongly acidic conditions (0.50 M H2SO4, pH 0.3). Uniform, multi-faceted CoP nanoparticles were synthesized by reacting Co nanoparticles with trioctylphosphine. Electrodes comprised of CoP nanoparticles on a Ti support (2 mg cm−2 mass loading) produced a cathodic current density of 20 mA cm−2 at an overpotential of −85 mV. The CoP/Ti electrodes were stable over 24 h of sustained hydrogen production in 0.50 M H2SO4. The activity was essentially unchanged after 400 cyclic voltammetric sweeps, suggesting long-term viability under operating conditions. CoP is therefore amongst the most active, acid-stable, earth-abundant HER electrocatalysts reported to date." @default.
- W4246087343 created "2022-05-12" @default.
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- W4246087343 date "2014-04-11" @default.
- W4246087343 modified "2023-09-25" @default.
- W4246087343 title "Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles" @default.
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- W4246087343 doi "https://doi.org/10.1002/ange.201402646" @default.
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