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- W4246127988 abstract "Competitive reactions of dimethyl ether ions are used to probe the steric and substituent effects of substituted phenols and anisoles in a quadrupole ion trap. The relative percentages of protonation and methylene substitution from the reactions of dimethyl ether ions show a correlation with size, location, and number of subsrituents on the aromatic ring. Although gas-phase basicity measurements of the phenols show no discernible correlation with the percentages of competitive reactions, semiempirical calculations show a good correlation between the trend in heats of formation and the trend in methylene substitution percentage. Reactions with deuterated compounds show that the methylene substitution reaction occurs on the ring." @default.
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- W4246127988 date "1995-08-01" @default.
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- W4246127988 title "Evaluation of steric and substituent effects in phenols by competitive reactions of dimethyl ether ions in a quadrupole ion trap" @default.
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- W4246127988 doi "https://doi.org/10.1016/1044-0305(95)00229-7" @default.
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