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• W4246143908 abstract "Abstract Epoxidieren leicht gemacht : Subnanometergroße Goldcluster auf amorphem Aluminiumoxid sind ein hoch aktiver und selektiver Katalysator für die Epoxidierung von Propen. Am höchsten ist die Selektivität bei Gasmischungen, die Sauerstoff und Wasser enthalten, sodass der Einsatz von Wasserstoff vermieden werden kann. Ab‐initio‐Dichtefunktionalrechnungen lieferten Informationen über Schlüsselintermediate und Reaktionswege. Demnach beruht die Aktivität des Katalysators auf der Bildung von Propenoxid‐Metallacyclen. Al grün, Au gelb, O rot, C grau. magnified image" @default.
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• W4246143908 date "2009-01-30" @default.
• W4246143908 modified "2023-10-18" @default.
• W4246143908 title "Selective Propene Epoxidation on Immobilized Au_6–10 Clusters: The Effect of Hydrogen and Water on Activity and Selectivity" @default.
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• W4246143908 doi "https://doi.org/10.1002/ange.200804154" @default.
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