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- W4246145220 endingPage "10083" @default.
- W4246145220 startingPage "10078" @default.
- W4246145220 abstract "Abstract Pd‐catalyzed hydroalkynylations were developed that involve ligand‐enabled regiodivergent addition of an alkyne to an allenamide, giving branched and linear products stereoselectively and facilitated by the neighboring amide group. Regioselectivity was achieved with the use of ( o ‐OMePh) 3 P and BrettPhos, which allowed the functionalization of various alkynes, including steroids, carbohydrates, alkaloids, chiral ligands, and vitamins. Based on the experimental results, it was proposed that hydro‐ and carbopalladation processes operated during the formations of the branched and linear products, respectively." @default.
- W4246145220 created "2022-05-12" @default.
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- W4246145220 date "2018-07-09" @default.
- W4246145220 modified "2023-10-12" @default.
- W4246145220 title "Regiodivergent Synthesis of 1,3- and 1,4-Enynes through Kinetically Favored Hydropalladation and Ligand-Enforced Carbopalladation" @default.
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- W4246145220 doi "https://doi.org/10.1002/ange.201805408" @default.
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