Matches in SemOpenAlex for { <https://semopenalex.org/work/W4246172854> ?p ?o ?g. }
- W4246172854 endingPage "181" @default.
- W4246172854 startingPage "165" @default.
- W4246172854 abstract "A series of tris-aryl phosphane oxides existing as residual enantiomers or diastereoisomers with substituents on the aryl rings differing in size and electronic properties were synthesized and characterized. Their electronic properties were evaluated on the basis of their electrochemical oxidation and reduction potentials together with those of the corresponding “blade bromides” (i.e., the naphthalene derivatives displaying the same substitution pattern of the tris-naphthyl phosphane oxide blades, with a bromo substituent where the phosphorus atom is located) determined by CV. The residual stereoisomeric phosphane oxides were isolated in a stereochemically pure state and were found to be highly configurationally stable at room temperature (stereoisomerization barriers of about 27 kcal mol−1). The chiroptical properties of the residual stereoisomers and the assignments of absolute configuration are discussed. The configurational stability of residual tris-aryl phosphane oxides was found to be scarcely influenced by the electronic properties of the substituents present on the aromatic rings constituting the blades, while steric effects play the most relevant role. Detailed theoretical calculations are in agreement with the experimental results and also contribute to a rational interpretation of the stereodynamics of these systems." @default.
- W4246172854 created "2022-05-12" @default.
- W4246172854 creator A5010249495 @default.
- W4246172854 creator A5013278095 @default.
- W4246172854 creator A5013506078 @default.
- W4246172854 creator A5017996020 @default.
- W4246172854 creator A5044323980 @default.
- W4246172854 creator A5045316082 @default.
- W4246172854 creator A5047421022 @default.
- W4246172854 creator A5078284237 @default.
- W4246172854 creator A5081562507 @default.
- W4246172854 date "2012-11-20" @default.
- W4246172854 modified "2023-10-17" @default.
- W4246172854 title "Steric and Electronic Effects on the Configurational Stability of Residual Chiral Phosphorus-Centered Three-Bladed Propellers: Tris-aryl Phosphane Oxides" @default.
- W4246172854 cites W1964755033 @default.
- W4246172854 cites W1966691144 @default.
- W4246172854 cites W1968209171 @default.
- W4246172854 cites W1974700168 @default.
- W4246172854 cites W1975450092 @default.
- W4246172854 cites W1980525113 @default.
- W4246172854 cites W1982332110 @default.
- W4246172854 cites W1988502210 @default.
- W4246172854 cites W2003494904 @default.
- W4246172854 cites W2007584072 @default.
- W4246172854 cites W2015806178 @default.
- W4246172854 cites W2016754252 @default.
- W4246172854 cites W2024642514 @default.
- W4246172854 cites W2025374262 @default.
- W4246172854 cites W2026713540 @default.
- W4246172854 cites W2030925452 @default.
- W4246172854 cites W2036327889 @default.
- W4246172854 cites W2049807213 @default.
- W4246172854 cites W2051682290 @default.
- W4246172854 cites W2055005400 @default.
- W4246172854 cites W2058804846 @default.
- W4246172854 cites W2060100607 @default.
- W4246172854 cites W2060503430 @default.
- W4246172854 cites W2065893607 @default.
- W4246172854 cites W2066370105 @default.
- W4246172854 cites W2071490394 @default.
- W4246172854 cites W2073243303 @default.
- W4246172854 cites W2083469020 @default.
- W4246172854 cites W2087726973 @default.
- W4246172854 cites W2091332072 @default.
- W4246172854 cites W2093188766 @default.
- W4246172854 cites W2099271981 @default.
- W4246172854 cites W2101370341 @default.
- W4246172854 cites W2112116841 @default.
- W4246172854 cites W2131350133 @default.
- W4246172854 cites W2139985973 @default.
- W4246172854 cites W2143627710 @default.
- W4246172854 cites W2149525902 @default.
- W4246172854 cites W2153996958 @default.
- W4246172854 cites W2159142039 @default.
- W4246172854 cites W2160790360 @default.
- W4246172854 cites W2167377347 @default.
- W4246172854 cites W2219719639 @default.
- W4246172854 cites W2325247056 @default.
- W4246172854 cites W2327528899 @default.
- W4246172854 cites W2907048863 @default.
- W4246172854 cites W3004632754 @default.
- W4246172854 cites W3005109520 @default.
- W4246172854 cites W4245003721 @default.
- W4246172854 cites W4256488793 @default.
- W4246172854 doi "https://doi.org/10.1002/chem.201201180" @default.
- W4246172854 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23165457" @default.
- W4246172854 hasPublicationYear "2012" @default.
- W4246172854 type Work @default.
- W4246172854 citedByCount "19" @default.
- W4246172854 countsByYear W42461728542013 @default.
- W4246172854 countsByYear W42461728542014 @default.
- W4246172854 countsByYear W42461728542015 @default.
- W4246172854 countsByYear W42461728542016 @default.
- W4246172854 countsByYear W42461728542017 @default.
- W4246172854 countsByYear W42461728542018 @default.
- W4246172854 countsByYear W42461728542019 @default.
- W4246172854 countsByYear W42461728542021 @default.
- W4246172854 countsByYear W42461728542022 @default.
- W4246172854 crossrefType "journal-article" @default.
- W4246172854 hasAuthorship W4246172854A5010249495 @default.
- W4246172854 hasAuthorship W4246172854A5013278095 @default.
- W4246172854 hasAuthorship W4246172854A5013506078 @default.
- W4246172854 hasAuthorship W4246172854A5017996020 @default.
- W4246172854 hasAuthorship W4246172854A5044323980 @default.
- W4246172854 hasAuthorship W4246172854A5045316082 @default.
- W4246172854 hasAuthorship W4246172854A5047421022 @default.
- W4246172854 hasAuthorship W4246172854A5078284237 @default.
- W4246172854 hasAuthorship W4246172854A5081562507 @default.
- W4246172854 hasConcept C138716334 @default.
- W4246172854 hasConcept C147597530 @default.
- W4246172854 hasConcept C178790620 @default.
- W4246172854 hasConcept C185592680 @default.
- W4246172854 hasConcept C192386470 @default.
- W4246172854 hasConcept C201194858 @default.
- W4246172854 hasConcept C2778689049 @default.
- W4246172854 hasConcept C2780263894 @default.
- W4246172854 hasConcept C2781014771 @default.
- W4246172854 hasConcept C2781076698 @default.