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- W4246290599 abstract "Silin im Visier: Das erste isolierbare, durch einen Phosphanliganden stabilisierte Silin wurde synthetisiert (siehe Bild). Eine Röntgenstrukturanalyse ergab eine sehr kurze Silicium-Kohlenstoff-Bindung, was mit Rechnungen zu SiC-Bindungen in Einklang ist. Die Verbindung ist zu einem gewissen Grad carbenisch, sodass das Phosphoniumsilaylid-Fragment als starker π-Donor und π-Akzeptor zu wirken scheint. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
- W4246290599 created "2022-05-12" @default.
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- W4246290599 date "2010-07-30" @default.
- W4246290599 modified "2023-10-14" @default.
- W4246290599 title "Synthesis and Structure of a Base-Stabilized C-Phosphino-Si-Amino Silyne" @default.
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- W4246290599 doi "https://doi.org/10.1002/ange.201003616" @default.
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